全文获取类型
收费全文 | 10454篇 |
免费 | 957篇 |
国内免费 | 2552篇 |
专业分类
化学 | 10241篇 |
晶体学 | 161篇 |
力学 | 1334篇 |
综合类 | 106篇 |
数学 | 527篇 |
物理学 | 1594篇 |
出版年
2024年 | 9篇 |
2023年 | 130篇 |
2022年 | 199篇 |
2021年 | 336篇 |
2020年 | 377篇 |
2019年 | 343篇 |
2018年 | 286篇 |
2017年 | 413篇 |
2016年 | 443篇 |
2015年 | 378篇 |
2014年 | 481篇 |
2013年 | 697篇 |
2012年 | 910篇 |
2011年 | 628篇 |
2010年 | 502篇 |
2009年 | 598篇 |
2008年 | 713篇 |
2007年 | 789篇 |
2006年 | 752篇 |
2005年 | 721篇 |
2004年 | 667篇 |
2003年 | 529篇 |
2002年 | 393篇 |
2001年 | 362篇 |
2000年 | 310篇 |
1999年 | 274篇 |
1998年 | 243篇 |
1997年 | 247篇 |
1996年 | 171篇 |
1995年 | 181篇 |
1994年 | 170篇 |
1993年 | 160篇 |
1992年 | 124篇 |
1991年 | 114篇 |
1990年 | 106篇 |
1989年 | 62篇 |
1988年 | 40篇 |
1987年 | 24篇 |
1986年 | 24篇 |
1985年 | 13篇 |
1984年 | 15篇 |
1983年 | 2篇 |
1982年 | 9篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 268 毫秒
21.
EQCM and voltammetric data show that thallium(I) ions, which are adsorbed in the region of the positive surface charge, most probably, in the form of the ionic pairs, are not reduced. In this potential region, thallium(I) ions are reduced directly from the solution. At more negative potentials, the previously adsorbed stable ionic pairs slowly undergo transition into the less stable form. From this form, thallium(I) ions can be reduced or desorbed into the solution. The process is best described by a model of one electron, i.e., full charge transfer. 相似文献
22.
Two-Layered Poly-o-phenylenediamine/Polyaniline Composite: Electrosynthesis and Spectroelectrochemical Properties 总被引:1,自引:0,他引:1
E. Yu. Pisarevskaya E. V. Ovsyannikova N. M. Alpatova 《Russian Journal of Electrochemistry》2004,40(9):969-976
Spectroelectrochemical properties of poly-o-phenylenediamine (PPD) and the synthesized composite of PPD and polyaniline—two chemically related polymers containing an amino-substituted benzene ring but having different conduction nature—are studied. The polyaniline synthesis on PPD-modified electrodes involves stages of the reaction initiation, the copolymer formation, and the formation of a polyaniline layer at the copolymer/solution interface. 相似文献
23.
Gui Hong YAN Da XING* Shi Ci TAN Institute of Laser Life Science South China Normal University Guangzhou 《中国化学快报》2004,15(1):101-104
Electrochemiluminescence (ECL), like other chemiluminescence technique, offers high signal-to-noise ratio. Furthermore, it has the advantage over other chemiluminescence techniques of being initiated by a voltage potential. Thus, it provides a better-controlled luminescence. This technique has been used in measuring many kinds of organic and inorganic matters, and analyzing many kinds of antigen, antibody and hapten, such as carcinoembryonic antigen and alpha-fetoprotein, etc1-6. The ele… 相似文献
24.
We analyse a model for equilibrium configurations of composite systems of nematic liquid crystal with polymer inclusions, in the presence of an external magnetic field. We assume that the system has a periodic structure, and consider the relaxed problem on the unit length constraint of the nematic director field. The relaxation of the Oseen–Frank energy functional is carried out by including bulk as well as surface energy penalty terms, rendering the problem fully non‐linear. We employ two‐scale convergence methods to obtain effective configurations of the system, as the size of the polymeric inclusions tends to zero. We discuss the minimizers of the effective energies for, both, the constrained as well as the unconstrained models. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
25.
Based on the discrete-structural theory of thin plates and shells, a calculation model for thin-walled elements consisting
of a number of rigid anisotropic layers is put forward. It is assumed that the transverse shear and compression stresses are
equal on the interfaces. Elastic slippage is allowed over the interfaces between adjacent layers. The solution to the problem
is obtained in a geometrically nonlinear statement with account of the influence of transverse shear and compression strains.
The stress-strain state of circular two-layer transversely isotropic plates, both without defects and with a local area of
adhesion failure at their center, is investigated numerically and experimentally. It is found that the kinematic and static
contact conditions on the interfaces of layered thin-walled structural members greatly affect the magnitude of stresses and
strains. With the use of three variants of calculation models, in the cases of perfect and weakened contact conditions between
layers, the calculation results for circular plates are compared. It is revealed that the variant suggested in this paper
adequately reflects the behavior of layered thin-walled structural elements under large deformations.
__________
Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 6, pp. 761–772, November–December, 2005. 相似文献
26.
V.I. Fernández A. Iucci C.M. Naón 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(1):53-56
We present an extension of the Tomonaga-Luttinger model in which left and right-moving particles have different Fermi velocities.
We derive expressions for one-particle Green's functions, momentum-distributions, density of states, charge compressibility
and conductivity as functions of both the velocity difference ε and the strength of the interaction β. This allows us to identify
a novel restricted region in the parameter space in which the system keeps the main features of a Luttinger liquid but with
an unusual behavior of the density of states and the static charge compressibility κ. In particular κ diverges on the boundary
of the restricted region, indicating the occurrence of a phase transition.
Received 20 May 2002 / Received in final form 23 August 2002 Published online 19 November 2002 相似文献
27.
With the use of an analytical approach developed, the influence of distribution of a tangential load on the stress concentration
in uniaxially tensioned flat specimens of high-strength unidirectional composites near the grips of a testing machine is evaluated.
In view of singularity of the analytical solution derived at the points of discontinuity of boundary conditions, for estimating
the stress concentration, it is suggested to employ the averaged value of longitudinal stresses, which is calculated by means
of an improper integral across the thickness of a near-surface layer.
__________
Translated from Mekhanika Kompozitnykh Materialov, Vol. 42, No. 6, pp. 787–796, November–December, 2006. 相似文献
28.
利用常规观测资料对1991~1996年江淮地区梅雨期的高、低层流场进行合成诊断分析,比较了高空偏北大风下有无暴雨在天气形势、物理量特征、三维流场方面的差异,文中一些分析结果可供暴雨预报参考。 相似文献
29.
Tatsuo Nakagawa Satoshi Fukura Munenori Nakai Kazumasa Sugiyama Ryohei Kokawa Hiroyuki Kagi 《Optical Review》2006,13(4):269-275
We constructed a scanning near-field optical microscope (SNOM) on a commercially available atomic force microscopy (AFM) apparatus
(SPM-9500J2; Shimadzu Corp.) to measure the stress distribution in ceramic composite materials. Features of our SNOM system
are: (1) a compact SNOM head substituted for the original AFM head; (2) a wide scanning range (125 × 125 μm2) inherited from the original scanner; (3) use of conventional shear-force regulation; (4) an optical system for the illumination-collection
(I-C) mode; (5) excitation by a 488 nm line of an Ar-ion laser, and (6) light detection by photon counting or a polychromator
equipped with an electronically cooled charge coupled device (CCD). This SNOM system was used to measure the surface structure
and stress distribution of an Al2O3/ZrO2 eutectic composite. We simultaneously measured topographic images and fluorescence spectra of an Al2O3/ZrO2 eutectic composite. We estimated its peak intensity, peak position, and peak width from the fluorescence spectrum during
scanning, which respectively correspond to the abundance of Al2O3, stress in the grain, and the anisotropy of that stress. Mapping images showed that the stress and its anisotropy were weaker
in the center of the Al2O3 grain than its boundary between Al2O3 and ZrO2. That observation suggests that Al2O3 underwent intense anisotropic stress induced by volume expansion in the phase transition of ZrO2 from the cubic phase to the monoclinic phase during preparation. 相似文献
30.
以石墨管为基体,十六烷基三甲基溴化铵为电活性物质,制备了带有内参比电极(Ag/AgC l)的管状流通式阴离子表面活性剂选择性电极,对其性能进行了测试。实验结果表明,其线性响应范围为1.6×10-7~5.1×10-3mol/L,斜率为52.0 mV/dec,检出限为2.0×10-8mol/L。利用该电极进行测试时,常用的无机阴离子C l-、SO42-、NO3-、PO43-等不会对其产生干扰;该电极适宜的pH值范围为2.50~10.50。对水样测定,回收率为95%~104%。电极可连续使用50 d左右。 相似文献